what role does DMSO play in the binding of O2 to [Co(II)salen]? which form of the dimer (A or B) do you think should be able to bind O2 in the solid state and why?

Answers

Answer 1

DMSO acts as a ligand in the binding of O2 to [Co(II)salen].

The dimer with less sterically hindered and more accessible for O2 binding and a more accessible cobalt ion and a more open binding pocket would be better suited for binding O2.

DMSO, or dimethyl sulfoxide, is often used as a solvent in biochemical and chemical processes. It acts as a ligand in the binding of O2 to [Co(II)salen].

It coordinates with the Co(II) center, allowing for the stabilization of the complex and facilitating O2 binding. This can make it easier for O2 to bind to the cobalt ion and form a complex.

Regarding the dimer forms (A or B), the less sterically hindered is more likely to bind O2 in the solid state due to its structure.

The form in which the Co(II) centers are less sterically hindered and more accessible for O2 binding compared to the Co(II) centers that are closer together, and creates steric constraints.

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Related Questions

The photograph shows a way individuals work together in groups.
Which term best describes the kind of work shown in the photograph?

The photograph shows a way individuals work together in groups.Which term best describes the kind of

Answers

Answer: Postindustrial

Explanation:

I just took the test hope this helps: )

Answer: A: Postindustrial

Explanation:

If we burn 1 gr of ethyl alcohol (C2H5OH) this will translate into a release of about 50 W of thermal energy of the flame that raise the temperature of the hot and cold reservoirs of a Sterling engine at 55 °C and 95 °C respectively. If at steady state the engine turns at about 240 rpm, its gears are shaped as rings of radius ~2 cm and weigh 50 gr, how efficient (in %) is the transfer of energy via flame?

Answers

Answer:

0.116%

Explanation:

efficiency of sterling engine = 1 - ( 55 + 273 )k / ( 95 + 273 ) k

                                               = 1 - ( 328 / 368 ) = 0.10869

Determine how efficient the transfer of energy via flame is

apply this relation ; energy of steady state / energy output  ---- ( 1 )

where;  energy output = efficiency of sterling engine * energy

                                     = 0.10869 * 50 = 5.4345 J/sec

energy of steady state = 1/2 * I * w^2  ------ ( 2 )

I = moment of inertia of engine = 2 * 10^-5 kgm^2

back to equation 2 :  

energy of steady state = 1/2 * ( 2 * 10^-5 ) * ( 240 * 2π / 60 )^2

                                      = 630.88 * 10^-5  J /sec

Input values into equation 1

= [ (630.88 * 10^-5 )  / 5.4345  ] * 100

= 0.116%

A) how many moles of water will be formed if you start with 2.54 moles of
sodium hydroxide and you have an excess of sulfuric acid?
showing work

Answers

2.54 moles of water will be formed if you start with 2.54 moles of sodium hydroxide and there is an excess of sulfuric acid. This is determined by using the concept of balanced chemical equation.

A balanced chemical equation can be defined as a chemical equation in which the number of each type of atom is equal on the two sides of the equation. The chemical formulas of the reactants and products that indicate the number of atoms of the preceding element.

We can write the balanced chemical equation for the reaction between sodium hydroxide and sulfuric acid as,

2 Na OH + H2SO4 → Na2SO4 + 2 H2O

From the above balanced chemical equation, it is clear that for every 2 moles of Na OH that react, 2 moles of H2O are produced.

here 2.54 moles of Na OH, we can calculate the amount of H2O produced can be determined as,

          = 2.54 moles Na OH x (2 moles H2O / 2 moles Na OH)

          = 2.54 moles H2O

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when 2 mol of a nonvolatile nonelectrolyte is dissolved in 5 mol of a solvent, the vapor pressure of the solution compared to that of the pure solvent is

Answers

When 2 mol of a nonvolatile nonelectrolyte is dissolved in 5 mol of a solvent, the vapor pressure of the solution compared to that of the pure solvent is lower.


This is because the presence of solute particles reduces the number of solvent particles at the surface, which in turn reduces the tendency of the solvent molecules to escape into the gas phase.
According to Raoult's law, the vapor pressure of the solution is proportional to the mole fraction of the solvent. Since the mole fraction of the solvent decreases when solute is added, the vapor pressure of the solution will be lower than that of the pure solvent.

For example, if the pure solvent has a vapor pressure of 100 torr, adding the solute would lower the vapor pressure of the solution to a value less than 100 torr.

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5. How many grams are in 0.719 moles of NaOH? ​

Answers

Answer: 28.7 moles

Explanation:

which period of the periodic table is completely made up of elements with no known stable ions?

Answers

Answer:

I think the answer is period 7

Explanation:

The period in periodic table, in which no stable ions of elements exists is 7th period. They contains actinides.

What are actinides?

Actinides are 7th period elements classified to F block of periodic table. A periodic table contains vertical columns called groups and horizontal rows called periods.  Each elements are classified into suitable groups based on their similarity in properties with other group elements.

There are four blocks in periodic table which are s, p, d and f block. S block elements are metals and d block contains transition metals and p block have non metals including gases and metalloids.

Actinides are f- block metals. All the elements in the period are radioactive. That's why they don't have a stable isotope or ion. They continuously undergo radioactive decay by the emission of charged particles.

Hence, the period containing unstable elements is 7th one.

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The procedure for examining the reaction of H_{2}O_{2} in the presence of Fe(NO_{3})_{3} instructed you to observe the mixture after bubbling ceases and then add an extra 3 mL of H_{2}O_{2} to the test tube Explain how these actions and your observations indicate the role of Fe(NO_{3})_{3} in the reaction

Answers

When the mixture of H₂O₂ and Fe(NO₃)₃ is bubbled, the reaction produces oxygen gas due to the oxidation of Fe(NO₃)₃.

What is oxidation?

Oxidation is a chemical reaction that involves the transfer of electrons from one molecule to another. It is essentially a reaction between an electron-donating molecule, known as the oxidant, and an electron-accepting molecule, known as the reductant. During an oxidation reaction, the oxidant gains electrons from the reductant, while the reductant loses electrons to the oxidant.

This can be seen by the bubbles rising from the tube. When the bubbling ceases, the reaction is complete and the Fe(NO₃)₃ has been completely oxidized. Adding an extra 3 mL of H₂O₂ to the test tube initiates the reaction again, showing that the Fe(NO₃)₃ is acting as a catalyst, speeding up the reaction but not being consumed in the process. This indicates that Fe(NO₃)₃ is playing the role of a catalyst in the reaction.

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3. What is the volume of a 2 M solution of CaCl2, contains 15 grams of CaCl2?

Answers

V = n : M

Mr CaCl₂ : 111 g/mol

n = mole = mass : Mr

V = 15 g/111 g/mol : 2 M

V = 0.068 L

4 The Mr of sodium hydroxide is 40. How many grams of sodium hydroxide are there in: a 500 cm³ of a molar solution? b 25 cm³ of a 0.5 M solution?​

Answers

There are 20 grams of Sodium hydroxide in a molar solution that has a volume of 500 cm3.

Sodium hydroxide – what is it? (NaOH)

Caustic soda and lye are two other names for sodium hydroxide. It is a typical component of soaps and cleansers. Sodium hydroxide seems to be a white, unscented solid at room temperature. Sodium hydroxide is a colorless, odorless liquid. Strong acids and water can cause explosive reactions with it.

Molarity is calculated by

moles (solute) / volume of solution in L

No. of moles = mass / molar mass

We have to find mass of sodium hydroxide (NaOH)

As we know, in 1 L (1000 cm³) of molar solution there is 40 gram of NaOH present.

From using this statement, 500 cm³ of a molar solution, means half liter of a molar solution contain -

= 40 / 2

= 20 gram of NaOH.

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which metal oxides can react with carbonmonoxide in the same way as zinc oxide​

Answers

Answer:The reaction of zinc oxide with carbon monoxide forms the product zinc metal and carbon dioxide. Zinc oxide is reduced to metallic zinc and carbon monoxide is oxidized to carbon dioxide.

Explanation:

Carbon nitride is not good to breathe in

how would you revise the stimulation so users can evaluate the role of human activity in the pH of the ocean

Answers

Answer:

Explanation:

If only one parameter can be changed in the simulation, it would be the global temperature. Human activities cause global warming and the temperature rise has caused the polar ice cap to melt. With more fresh water going into the oceans due to melting ice cap, there is a big impact on the pH.

Answer:

Explanation:

increase CO2 in atmosphere - human activity like driving cars n burning fossil fuel releases air polluntants. CO2, NOx n SO2 are all soluble in water n form acids. of the 3, CO2 is the most common pollutant n has the most effect on the pH in oceans.

Question 5
What is the correct way to set up the relationship between milligrams and grams?
10-mg-1g
O None are correct
10-3mg-1g
1mg-10-³g
O 1mg-106g
O
5 pts
Next ▸

Answers

The correct way to set up the relationship between milligrams and grams is 1mg-10-³g. option D is correct.

What are  milligrams and grams ?

The milligrams and grams are is eual to the 1g = 1,000mg. 1,000 milligrams (mg) in 1 gram (g).

The conversion of  your gram figure to milligrams multiply your figure by 1000.  1mg is 1/1000g. There are 1,000 milligrams in 1 gram.

Therefore, The correct way to set up the relationship between milligrams and grams is 1mg-10-³g. option D is correct.

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If 17.2 g of NaI (MM = 149.89 g/mol) are added to a 500.0 mL volumetric flask, and water is added to fill the flask, what is the concentration of NaI in the resulting solution?

Answers

Taking into account the definition of molarity, the concentration of NaI in the resulting solution is 0.23 moles/L.

Definition of molarity

Molarity is a measure of the concentration that indicates the number of moles of solute that are dissolved in a given volume.

The molarity of a solution is calculated by dividing the moles of solute by the volume of the solution:

molarity= number of moles÷ volume

Molarity is expressed in units moles/L.

Definition of molar mass

The molar mass of substance is a property defined as the amount of mass that a substance contains in one mole.

Concentration in this case

The molar mass of NaI is 149.89 g/mole. You have a mass of NaI of 17.2 g. So, the amount of moles can be calculated as:

amount of moles= 17.2 g÷ 149.89 g/mole

amount of moles= 0.115 moles

You know that the volume of the solution is 500 mL of 0.500 L (being 1000 mL= 1 L). Replacing in the definition of molarity:

molarity= 0.115 moles÷ 0.500 L

Solving:

molarity= 0.23 moles/L

Finally, the concentration of the compound is 0.23 moles/L.

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equatinal by elimination melha
8n-3y = 18 and5x+6y=27

Answers

Answer:

x = 3 and y= 2

Explanation:

Given equations:

           8x - 3y  = 18  - ---- (I)

           5x + 6y = 27 -------(II)

Solve this problem by elimination;

  In the elimination method, we simply find a common term that can make one of the variables in the two equation the same. Then we either add or subtract to remove the variable.

 Mulitply equation (i) by 5 to give equation III

 Mulitply equation (II) by 8 to give equation IV

     5(8x - 3y) = 5(18) ------- III

     8(5x + 6y) = 8(27) ------- IV

   40x - 15y = 90------- III

   40x + 48y = 216  ------- IV

Subtract  equation III and IV;

        -15y - 48y = 90 - 216

         - 63y = -126

                y = 2

Solve for x;

      40x - 15y = 90;

       40x - 15(2) = 90

         40x - 30 = 90

           40x = 90 + 30

              40x = 120

                 x = 3

What is the mass of 23 moles of lithium atoms

Answers

Take 23mols and multiply it by the atomic mass of Li:

23mol  * 6.94g/mol = 159.62g

Identify two of the basic concepts of democracy. Explain what each one means. Draw a picture representing one of the basic concepts of democracy. Explain what the picture represents.

Plss help

Answers

Basic concepts of democracy are  freedom of assembly, association, property rights, freedom of religion and speech, inclusiveness and equality.

What is democracy?

Democracy is a form of government in which the people have the authority to deliberate and decide legislation ("direct democracy"), or to choose governing officials to do so ("representative democracy"). Who is considered part of "the people" and how authority is shared among or delegated by the people has changed over time and at different rates in different countries.

Features of democracy often include freedom of assembly, association, property rights, freedom of religion and speech, inclusiveness and equality, citizenship, consent of the governed, voting rights, freedom from unwarranted governmental deprivation of the right to life and liberty, and minority rights.

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What statement about models of isotopes below is accurate?

A- Each picture represents a different element because they have different numbers of neutrons

B- each picture represents an isotope of carbon because they each have 6 protons

C- each picture represents an isotope of lithium because they each have 3 protons

What statement about models of isotopes below is accurate? A- Each picture represents a different element

Answers

Answer : The correct option is (C) each picture represents an isotope of lithium because they each have 3 protons.

Explanation :

Isotope : It is defined as the element that have the same number of protons but have the different number of neutrons of each of the atom.

As in the given picture, the number of protons are same but number of neutrons are different.

As we know that atomic number is either equal to number of protons or electrons for neutral atom.

The number of protons in the given picture are 3.

So, the element will be lithium with atomic number 3 and all are the isotopes of lithium.

Hence, the correct option is (C) each picture represents an isotope of lithium because they each have 3 protons.

how many oxygen atoms are in one mole of o_2 molecules?

Answers

A mole of oxygen (\(O_{2}\)) molecules contains 6.022 x 10^23 oxygen atoms.

This number is known as Avogadro's number, and it is the number of atoms or molecules that make up one mole of any substance.

To calculate the number of oxygen atoms in one mole, we multiply Avogadro's number by the number of oxygen atoms in one molecule of oxygen (2).

This gives us 12.044 x 10^23 oxygen atoms in a mole of oxygen molecules.

The significance of Avogadro's number is that it allows us to compare the number of atoms or molecules between two different substances.

For example, if we know that one mole of oxygen molecules contains 12.044 x 10^23 oxygen atoms, and one mole of hydrogen molecules contains 6.022 x 10^23 hydrogen atoms, we can determine that two moles of hydrogen molecules will contain the same number of atoms as one mole of oxygen molecules.

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The best option for a donor organ would be _____.

Answers

Answer:

Most likely a heart or lung

Explanation:

a lot of people have a lot of heart problems and hearts are the most vital organ in your body. without your heart you could not live and your heart has a tissue tear it could be lethal causing death

A gymnast whose weight is 5 10 N hangs from the middle of a bar supported by two vertical strands of rope. What is the tension in each strand?

A. 765 N
B. 0 N
C. 1020 N
D. 510 N
E. 255 N

Answers

Answer:

I think the answer is(D. 510 n)

the half-life for the transmutation of radon-222 () to lead-214 () is 3.8 days. if there is an initial mass of 100.0 g of radon-222, how much radon-222 would remain after 1.9 days?

Answers

The half-life for the transmutation of radon-222 that would remain after 1.9 days is approximately 70.71 g.

To calculate the transmutation of radon-222 that would remain after 1.9 days, we can use the concept of half-life.

Half-life of radon-222 (t½) = 3.8 days

Initial mass of radon-222 = 100.0 g

Time elapsed (t) = 1.9 days

The number of half-lives elapsed can be calculated as:

Number of half-lives (n) = t / t½

Substituting the values:

n = 1.9 days / 3.8 days = 0.5

Now, we can calculate the remaining mass of radon-222 using the formula:

Remaining mass = Initial mass × (0.5)^n

Substituting the values:

Remaining mass = 100.0 g × (0.5)^0.5 ≈ 70.71 g

Therefore, approximately 70.71 g of radon-222 would remain after 1.9 days.

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Finding mole ratios from chemical formulae
This is the chemical formula for nickel tetracarbonyl (a powerfully poisonous liquid used in nickel refining):
Ni(CO)4
A chemical engineer has determined by measurements that there are 93. moles of carbon in a sample of nickel tetracarbonyl. How many moles of oxygen are in
the sample?
Round your answer to 2 significant digits.

Finding mole ratios from chemical formulaeThis is the chemical formula for nickel tetracarbonyl (a powerfully

Answers

7 moles of oxygen are in the sample.

According to the chemical formula, each mole of nickel tetracarbonyl contains 4 moles of C atoms. Simply convert it into a fraction by putting the original solution in the denominator and the diluted solution in the numerator if you need to determine the concentration ratio between two solutions. The V/n ratio for each gas must be the same if the two gases are at the same temperature and pressure. The volume ratio of two gases at the same temperature and pressure is equal to their molar ratio. The mole ratio of C to O is 1 : 1

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When 10 moles HCl reacts with Ca(OH) 2 how many moles of H_{2}*O are made?

Answers

The amount of Ca(OH)₂ produced = 5.2 g which is calculated in the below section.

NUMBER OF MOLES of HCl = Molarity of solution x Volume of Solution

# of moles of HCl = (0.40 mol/L ) x 350 mL

                              = (0.40 mol/L ) x 0.350 L

                              = 0.14 mol

The mass of HCl that makes 0.14 mol of HCl

Mass of HCl= # of moles x molar mass of HCl

Mass of HCl = 0.14 mol x 36.5 g/ mol

Mass of HCl = 5.11g

As per Stoichiometry , 1g of HCl reacts with 1.015 g of Ca (OH)₂

So, 5.11g of HCl can react with 5.11 x 1.015  g

                                                 = 5.1865 g or 5.2 g of Ca(OH)₂

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Suppose you see a crescent Moon. How do you know if it is waxing or waning?

Answers

Answer:

waxing is in the evening and waning is in the morning if you cant see the moon in the evening it is waning if you can see it in the evening it is waxing

what are the affects of increasing thermal energy B

Answers

Answer:

The molecules tend to speed up and move faster throughout the substance once thermal energy increases. This is evident whenever we heat up water as its molecules tend to move faster throughout the water as thermal energy tends to increase

Hope this helps!

How can the wetland reduce flooding and what impact could this have on future generations?

Answers

Answer:

Wetlands trap the surface water, snowmelt, rain, groundwater, and flood water. They then slowly release the water. Wetland vegetations like trees and root mats also help in controlling the speed of flood water and release it slowly on the floodplain.

Explanation:

If the number of atoms of each element on the reactant side of an equation is equal to the number of atoms of each element on the product side of the equation, the equation is _____.

A.)endothermic
B.)equal
C.)balanced
D.)exothermic

Answers

C. Is your answer hope you have a wonderful day

What is the net ionic equation for the reaction shown below?
AgNO3(aq) + NaCl(aq) --> AgCl(s) + NaNO3(aq)

Answers

Answer:

Ag⁺(aq) + Cl⁻(aq)       →      AgCl(s)  

Explanation:

Chemical equation:

AgNO₃(aq) + NaCl(aq)       →     AgCl(s) + NaNO₃(aq)

Balance chemical equation:

AgNO₃(aq) + NaCl(aq)       →     AgCl(s) + NaNO₃(aq)

Ionic equation

Ag⁺(aq)+ NO₃⁻(aq) + Na⁺(aq)+ Cl⁻(aq)       →      AgCl(s)  + Na⁺(aq)+ NO₃⁻(aq)

Net ionic equation:

Ag⁺(aq) + Cl⁻(aq)       →      AgCl(s)  

The NO₃⁻((aq) and Na⁺ (aq) are spectator ions that's why these are not written in net ionic equation. The AgCl can not be splitted into ions because it is present in solid form.

Spectator ions:

These ions are same in both side of chemical reaction. These ions are cancel out. Their presence can not effect the equilibrium of reaction that's why these ions are omitted in net ionic equation.  

Suppose you forgot to wipe off fingerprints from the surface of the unknown sample vial before putting it into the MicroLAB sample chamber. a. Describe how the absorbance measurement of the unknown would be affected by this error. ** b. State how the concentration of your unknown solution will be affected, i.e., would the concentration calculated by the MicroLAB software be higher or lower than it actually is

Answers

The presence of fingerprints on the surface of the unknown sample vial that were not cleaned off prior to being placed in the MicroLAB sample chamber would have an effect on the absorbance measurement of the unknown.

The absorbance measurement of the unknown would be affected by this error in the following ways: Since the fingerprints are not a part of the actual sample, their presence in the sample chamber can result in light scattering. The amount of light absorbed by the sample will decrease due to this, resulting in a lower absorbance measurement.

The absorbance measurement is inversely proportional to the amount of light absorbed by the sample, meaning that a decrease in absorbance measurement would result in an increase in the amount of light that passes through the sample. Therefore, a lower absorbance reading would result in a higher concentration value than the actual value of the unknown solution.

Hence, the concentration calculated by the MicroLAB software would be higher than it actually is.

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you are reading your aceable course and come across this: 475.021, f.s. what is this mysterious glyph trying to tell you?

Answers

475.021, f.s., refers to the Florida Statute (f.s.) for driver's license suspensions and revocations. This particular statute deals with the suspension of licenses for drivers who fail to pay court fines, costs, and fees.

The statute states that failure to pay the required court fees within 30 days will result in the suspension of the driver's license.

After 90 days, the suspension becomes permanent until the fees are paid. In summary, the mysterious glyph is trying to tell you about the legal statute in Florida regarding the suspension of driver's licenses for non-payment of court fees, fines, and costs.

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Ana is planning to give her informative speech in a few days. Prior to speech day, she visits the room in which she will give the speech to check out the size and layout of the room, as well as if the projector is working properly. Ana is concerned with the __________ dimension of communication. How can these ideas of silence, fear, and guarding your thoughts be applied to what was happening with the German people during the Nazi regime and the Holocaust? Explain in 3-5 sentences. McCullough, David. Mornings on Horseback. New York: Simon & Schuster, 1981. Print.If an author uses an attributive phrase, including the authors name, to introduce a brief quote from page 59 of this source, which of the following is the correct MLA style in-text citation?A (59)B (McCullough 59)C (McCullough 1981: 59)D (McCullough, Mornings on Horseback, 59) T/F ketosis is an excess of ketone bodies in the blood and urine, which is often seen in uncontrolled diabetes mellitus and starvation need help now lol!!! Animal cells are considered eukaryotic, and bacteria cells are considered prokaryotic. The difference between these two cell types is that What is the perimeter of triangle PQR? Round to the nearest tenth if necessary A. 25.6 units B. 28 units C. 24 units D. 27.3 units *if possible please show work* during the 1990s, an average of 4 million babies are born annually in a country. the average child goes through 7,800 diapers in the first 130 weeks of life (2.5 years) until toilet training or 60 per week (deveny, 1990). (a) what is the annual market potential for disposable diapers? (b) what other qualitative issues need consideration here? pleaseeee helpppppp meeee Help please!! Ill give brainliest!! What inference about Haida families can be drawn from the actions of the sky chief? how do Solar radiation and convection currents work together to form weather patterns and help plants grow. Why did early farmers use slash-and-burn agriculture?A. to keep undergrowth from drying out the earthB. to get rid of pestsC. to keep the soil fertileD.to get rid of old crops Do you think these fish are an example of natural selection among two populations of the same species approximately 10.5% of american high school students drop out of school before graduation. assume the variable is binomial. choose 15 students entering high school at random. find these probabilities. round intermediate calculations and final answers to three decimal places. part: 0 / 30 of 3 parts complete part 1 of 3 (a) at least 13 graduate Please help I don't understand! What is the area of the shape below One serving of peanuts has about 166.000 calories. Convert this to Joules.[answer: 695,000 J]please show me the work! thank youu! a polyphase synchronous motor has three stator windings that are Problems: 1. Write a method to recursively creates a String that is the binary representation of an int N. 2. Create a method to draw a Sierpinski carpet. 3. Solve the Tower of Hanoi puzzle using recursion