There are two main types of covalent bond breakage. In homolytic breakage (as in Table 9.2, p. 371), each atom in the bond gets one of the shared electrons. In some cases, the electronegativity of adjacent atoms affects the bond energy. In heterolytic breakage, one atom gets both electrons and the other gets none; thus, a cation and an anion form.
(b) Use bond energy and any other data to calculate the enthalpy of reaction for the heterolytic cleavage of O₂.

Answers

Answer 1

The heat of reaction for the heterolytic energy of O₂ is 1420 KJ / mol.

What is heterolytic cleavage?

Hetrolytic bond cleavge needs more amount of energy as compared to homolytic bond cleavage . The C — C bond in CH3 – CF3 is more polar as compared to C – C bond in ethane. This is due to the reason that the presence of highly electronegative atom of F. Polar species like CH3 – CF3 undegoes heterolytic bond cleavage. Therefore, the C – C bond in CH3 – CF3 need more energy to cleave bond and is the stronger.

In a heterolytic bond cleavage step, one atom gets the set of electron which is initially made up of the C – C bond . This cleavage produces the cationic oxygen and the heat of reaction for the heterolytic energy of O₂ is 1420 KJ / mol and produces an anionic oxygen . This heterolytic bond cleavage of O2 can be calculated by the adding of the energies which is associated with the homolytic bond cleavage of O2 first ionization energy and electron affinity.

In mathematical way,

∆ H = ( Homolytic bond cleavage + electron affinity + first ionization energy )

Where,

∆H is the heat of reaction associated with enthalpy

By Substituting all the values, we get

∆H = 498 KJ / mol / 2 + (- 141 KJ / mol

= 1420 KJ / mol

Thus, we calculated that the heat of reaction for the heterolytic energy of O₂ is 1420 KJ / mol.

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Related Questions

What is force? Why?​

Answers

In physics, a force is any interaction that, when unopposed, will change the motion of an object. A force can cause an object with mass to change its velocity to accelerate. Force can also be described intuitively as a push or a pull. A force has both magnitude and direction, making it a vector quantity.

how many allylic halides (including stereoisomers) can be formed when 3-methylcyclohexene undergoes allylic halogenation with one equivalent of nbs, peroxide, and light?

Answers

When 3-methylcyclohexene undergoes allylic halogenation with one equivalent of NBS (N-bromosuccinimide), peroxide, and light, it can form two allylic halides.

The reaction involves the addition of a bromine atom to the allylic position of the alkene. The two possible products are formed by the addition of the bromine atom to the two different allylic carbons in the 3-methylcyclohexene molecule.

The two allylic halides that can be formed are:

1-Bromo-3-methylcyclohexene (with the bromine atom attached to the allylic carbon adjacent to the methyl group).

1-Bromo-1-methylcyclohexene (with the bromine atom attached to the allylic carbon adjacent to the non-methyl substituted carbon).

These two compounds are stereoisomers of each other since they have the same connectivity but differ in the spatial arrangement around the double bond.

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Precautions List precautions and explain why they were taken:
when adding water to the rock salt.
during the filtration stage.
during (i) evaporation to dryness and (ii) crystallisation.​

Answers

Precautions when adding water to rock salt: Add water slowly and carefully to avoid splashing ; Precautions during filtration stage: Use filter paper that fits the funnel properly ; Precautions during (i) evaporation to dryness and (ii) crystallization: Avoid overheating solution during evaporation and stirring the solution.

What is meant by evaporation?

Physical process by which a liquid substance is transformed into  gaseous state is called evaporation.

Precautions and their explanations:

Precautions when adding water to rock salt:

Add water slowly and carefully to avoid splashing or spilling.

Use a stirring rod to dissolve salt crystals completely.

Explanation: Rock salt can be quite reactive with water, and adding too much water too quickly can cause the solution to boil or splatter. Using a stirring rod helps to dissolve salt crystals completely without creating too much agitation.

Precautions during filtration stage:

Use a filter paper that fits the funnel properly and fold it properly.

Avoid touching filter paper with your fingers.

Explanation: The filter paper needs to fit the funnel properly to ensure that all of the liquid is filtered properly.

Precautions during (i) evaporation to dryness and (ii) crystallization:

Avoid overheating solution during evaporation and stirring the solution.

Use a clean glass rod to encourage crystallization and avoid scratching the walls of the container.

Explanation: Overheating the solution can cause the salt to decompose or change its chemical properties. Stirring the solution can also lead to the formation of smaller crystals.

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Need quickly!
what is the name of pb(no3)2? explain how you determined the bond type and the steps you used to determine the naming convention for the compound.

Answers

The name of pb(no3)2 is Lead(II) nitrate.

Type of bond:

pb(no3)2 is an ionic compound.

How to name ionic compound?

The name of an ionic compound is written as its cation followed by anionThe charge of cation should be written in Roman lettersThe net charge of ionic compounds is generally zero

Name of pb(no3)2:

The charge of nitrate ion NO3 is -1. To find the charge of lead, we'll take it as x. Hence,

x+2(-1)=0

x=2

The charge of lead cation in this ionic compound is calculated as +2.

Therefore the name of pb(no3)2 is confirmed as Lead(II) Nitrate.

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Ben makes five paper helicopters with different wing lengths. He drops them the same way from a height of two meters for five trials each. He records the amount of time it takes for each helicopter to fall to the ground. What is the independent variable?

Answers

Answer:

Wing length

Explanation:

According to the given excerpt, independent variable is 'wing length' and dependent variable is 'amount of time it takes for helicopter to hit the floor'.

Independent variable refers to the variable that do not undergo any change or shift in the course of the experiment of research. The other variables are measured using the constant independent variable. The value obtained from the independent variable is independent. On the other and, the dependent variable witnesses change with respect to the independent variable.

how much casein did you obtain (actual yield in mg) from 240ml (1cup) of whole milk? make sure that your casein product is completely dry before measurement. wet product might add the mass of water that could result more than 100% percent yield

Answers

To determine the actual yield of casein in mg from 240 ml of whole milk, the given milk should be processed to remove the casein completely.The mass of the empty container should then be deducted from the mass of the container containing the dried casein to obtain the actual yield of casein.

The following steps are required to obtain the actual yield of casein in mg from 240 ml of whole milk: Measure 240 ml (1 cup) of whole milk. Add 10 ml of 1M acetic acid and stir well. Filter the milk using filter paper to obtain the curd. Dry the curd completely by keeping it in an oven for some time. Weigh the dried curd to obtain the actual yield of casein in mg.

To prevent the mass of water from being added to the dried curd, the product must be completely dry before measurement. Otherwise, the wet product might add the mass of water, resulting in more than 100% yield.The yield of casein is determined by subtracting the weight of the empty container from the weight of the container containing casein. The mass of the empty container should be deducted from the mass of the container containing the dried casein to obtain the actual yield of casein.

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Which correctly describes latent heat? O A. The heat of molecules that are under pressure O B. The heat used to change the temperature of a liquid O C. The heat held inside of ice crystals colder than -2°C O D. The heat absorbed or lost by a substance while it's changing state

Answers

The correct answer that describes latent heat is that it is the heat absorbed or lost by a substance while it is changing state.

correct answer is option D.

Latent heat refers to the amount of heat absorbed or released by a substance during its phase transition (changing from one state to another) without altering its temperature. The term "latent" means "hidden," indicating that the energy involved in the phase transition is not directly related to temperature. It is released or absorbed as the result of the transformation of the substance's internal energy. When changing from a solid to a liquid state or from a liquid to a gas state, energy is absorbed by the substance, while when changing from a gas to a liquid state or from a liquid to a solid state, energy is released. So, in conclusion, latent heat is the heat absorbed or lost by a substance while it is changing state.

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What are two factors that can change the rate of a chemical?

Answers

Answer:

the surface area of a solid reactant.

temperature.  

presence/absence of a catalyst.

Draw the electron dot structure of the hydroxide ion (OH-).

Answers

Answer:

X = electrons from hydrogen

O (black) = electrons from oxygen

O (red) = electrons from when it was connected to a metal atom, hence why it has a negative charge

Draw the electron dot structure of the hydroxide ion (OH-).

(1. balancing chemical equations) why do we go through all this trouble to learn an algebraic method to balance chemical equations, instead of using the easy and simple trial-and-error method? group of answer choices it is general enough to balance any chemical equations, regardless of the complexity. this is programmable so that we can ask computer to help. we can analyze whether a reaction can actually be balanced. guess we just need to do some math anyway dr. chan just wants to make things more complicated so that he will be very happy when he sees us not knowing how to solve problems.

Answers

The reason we learn an algebraic method to balance chemical equations instead of using a trial-and-error method is because the algebraic method is more efficient and reliable.



Using trial and error can be time-consuming and may not always lead to the correct solution. Balancing chemical equations requires ensuring that the number of atoms of each element on both sides of the equation is equal. This can become complex when dealing with more complicated equations.

The algebraic method, on the other hand, provides a systematic approach that can be applied to any chemical equation, regardless of its complexity. By applying mathematical principles and using variables, we can determine the correct coefficients to balance the equation. This method is programmable, which means we can use computer algorithms to solve equations more quickly and accurately.

Additionally, the algebraic method allows us to analyze whether a reaction can actually be balanced. It helps us understand the stoichiometry of the reaction and determine the correct ratios of reactants and products.

Contrary to the belief that it is only meant to complicate things, learning this method is essential for a deeper understanding of chemistry and problem-solving skills. It enables us to apply logical thinking and mathematical concepts to chemical reactions, which is crucial in various scientific and industrial applications.

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Under conditions of extreme heat and pressure, sedimentary rock can transform into metamorphic rock. True or false?

Answers

Answer:

Sedimentary rocks like bituminous coal, limestone, and sandstone, given enough heat and pressure, can turn into nonfoliated metamorphic rocks like anthracite coal, marble, and quartzite. Nonfoliated rocks can also form by metamorphism, which happens when magma comes in contact with the surrounding rock

Explanation: THEREFORE I'D SAY TRUE!

which element is oxidized in this reaction? zno c→zn co enter the chemical symbol of the element.

Answers

In the reaction Zn + CO → ZnO + C, the element that undergoes oxidation is carbon (C).

Which element is oxidized in the reaction Zn + CO → ZnO + C?

In the reaction Zn + CO → ZnO + C, the element that undergoes oxidation is carbon (C).

During the reaction, carbon (C) in carbon monoxide (CO) is oxidized from an oxidation state of +2 to +4, forming carbon dioxide (CO2).

Oxidation refers to the loss of electrons or an increase in the oxidation state of an element. In this case, carbon gains oxygen and its oxidation state increases from +2 to +4. O

n the other hand, zinc (Zn) undergoes reduction since it gains oxygen and its oxidation state decreases from 0 to +2.

This reaction involves both oxidation and reduction processes, and carbon is the element that is oxidized.

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If a 1.0 L canister holds 2.0 moles of gas, and the temperature of the gas is 500. C, what is the pressure inside the container in atm

Answers

The pressure of the gas inside the canister can be determined using the ideal gas equation. The pressure inside the canister is 126.7 atm.

What is ideal gas equation ?

Ideal gas equations states the relation between volume, pressure, temperature and number of moles of gas as written below:

PV = nRT.

Where R is the universal gas constant equal to 0.082 L atm/K mol.

Given the volume of the tank  V = 1 L

number of moles n = 2 moles

temperature = 500 ° C = 773 k

Then pressure P = nRT/V.

Pressure of  gas = 2 moles ×773 K× 0.082 L atm/K mol /(1 L)

P = 126 atm.

Therefore, the pressure of the gas in the canister is 126 atm.

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An ionic bond is the attraction between _____.

Answers

Answer:

oppositely charged ions in a chemical compound

Explanation:

Answer:

Between ions

Explanation:

the density of a certain gaseous fluoride of phosphorus is 3.93 g/l at stp. calculate the molar mass of this fluoride and determine its molecular formula. answer

Answers

The molar mass of the compound is 88 g/mol and the formula of the compound is  \(P_{2} F_{2}\).

What is the molar mass of the gas?

We know that the ideal gas equation is the equation that we can be able to obtain any of the parameters that has to do with a gas. In this case, we have the gas that we are told that it is a certain gaseous fluoride of phosphorus and that the density of the gas is about  3.93 g/l

Given that;

MM = dRT/P

MM = molar mass

d = density of the gas

R = gas constant

T = temperature

P = pressure

Then we have to be able to substitute the values as shown;

MM =  3.93  * 0.082 * 273/1

MM = 88 g/mol

The formula of the gas is obtained from;

[PF]n = 88

[31 + 19]n = 88

50n = 88

n = 88/50

n = 2

The molecular formula of the compound is \(P_{2} F_{2}\).

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Chemistry Solutions and Reaction Rates

Chemistry Solutions and Reaction Rates

Answers

Answer:

D. decreasing the surface area of Zn

Explanation:

Because zinc is a reactant in the reaction, decreasing its surface area would decrease the production rate of ZnCl₂ - there are fewer particles exposed to the hydrochloric acid so there is a smaller chance of particles colliding which means there are fewer successful collisions per second.

Hope this helps!

How do you think the light would travel if the laser pointer was 1000 meters away?
20 pnts!!!!!!!!!!!!!!!!!!!!!

Answers

It totally depends on the laser power (mW). The divergence of the light is depending on it.

What is a laser?

A device that uses stimulated emission of photons from excited atoms or molecules to produce a strong beam of coherent monochromatic light is a laser.

When electrons in optical materials like glass, crystal, or gas absorb energy from an electrical current or light, a laser is formed.

When a 5mW 650 nm laser glows on a white surface in complete darkness, we can see it from 500 to 1 km distant.

Because of the divergence, the projected dot 1 km distant will be a huge dot with a diameter of 20–30 m30 m and will be extremely dim.

Hence,It totally depends on the laser power (mW). The divergence of the light is depending on it.

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. zinc + nitrogen → zinc nitride

. zinc + nitrogen zinc nitride

Answers

Answer:

...................

.

. zinc + nitrogen zinc nitride

Which of the following is a sign that a chemical change is taking place?
Select one:

A.
a substance melting at high heat

B.
an object breaking into pieces

C.
a blue solid dissolving in water and changing the water to a blue colour

D.
an offensive odor emitting after two liquids are mixed

Answers

B. an object breaking into pieces

Answer:

C. a blue solid dissolving in a water and changing the water to a blue colour

Explanation:

A olvent i found to be 50. 0% oxygen, 37. 5% carbon, and 12. 5% hydrogen. What i the empirical formula of thi olvent

Answers

The empirical formula of the solvent is CH4.

Relative number of atoms

Of H= 25/1 = 25

Of C= 75/12 = 6.25

What is a solvent?

Solvents are a heterogeneous group of structurally different chemicals that can be used to dilute, dissolve, or disperse other compounds. The ability of a solvent to dissolve another molecule depends on the molecular structure and physical properties of both the solvent and the solute. Solvents can be categorized as organic or inorganic and in terms of chemical polarity. Polar solvents include water, alcohols, and other chemicals containing –OH, such as acetic acid, which have the ability to donate H+ and form hydrogen bonds. Polar solvents lacking the –OH group, including acetonitrile, dimethylformamide, and dimethylsulfoxide, are protophilic solvents and are used to dissolve less polar solutes.

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Some of the brine is encapsulated within ice crystals, but most is trapped in the spaces between neighboring crystals. When air temperature falls below 0°C, the brine migrates downward, toward the higher water temperatures below. Eventually, the high-density brine drains into the water beneath the ice. In the process, the sea ice freshens while the salinity of the underlying water. and becomes
a increases less dense
b
increases
more dense
c. decreases less dense
d. decreases
more dense

Answers

The high-density brine drains into the water beneath the ice and in the process, the sea ice freshens while the salinity of the underlying water decreases, becoming less dense (Option C).

Sea ice is usually less salty than the ocean water it freezes from. During the process of ice formation, salt in the ocean water is expelled from the ice as it grows; most of the salt is ejected into the ocean but some remain trapped inside pockets of brine within the ice. When the air temperature falls below the freezing point of seawater (usually around -1.8 °C), water molecules start to form ice crystals, which grow and aggregate into a solid sheet of ice.

During this process, the salt rejected by the growing ice also accumulates, causing the salinity of the remaining brine to increase. Some of the brine is encapsulated within ice crystals, but most are trapped in the spaces between neighboring crystals.

Thus, the correct option is C.

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what is the hazardous substance in automobile exhaust that is also present in high concentrations in tobacco smoke?

Answers

The hazardous substance in automobile exhaust that is also present in high concentration in tobacco smoke is acrolein.

Substance that tobacco smoke and the exhaust of automobiles contains a has it is substance called acrolein in very very high concentration.

Inhaling acrolein can give rise to several breathing problems like shortness in breathing and also irritation in lungs.

Acrolein is formed when the fats are overheated apart from automobiles and tobacco a very low amount of acrolein is also found in over used cooking oil.

To reduce acrolein from the automobile exhaust lead based adsorption substances are preferred to be used in automobile exhaust.

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A radioactive sample has activity 4.20kBq and half-life 32 minutes. Measurements are taken every 5 minutes for one hour. Plot a graph of the activity against time for this sample.

Answers

Plotting the graph of activity against time for a radioactive sample with an initial activity of 4.20 kBq and a half-life of 32 minutes, with measurements taken every 5 minutes for one hour, shows a decreasing exponential curve.

The activity of a radioactive sample decreases exponentially over time according to the formula A(t) = A0 * (1/2)^(t / T), where A(t) is the activity at time t, A0 is the initial activity, t is the time elapsed, and T is the half-life.

In this case, the initial activity A0 is 4.20 kBq and the half-life T is 32 minutes. Measurements are taken every 5 minutes for one hour, which corresponds to 12 measurements in total.

To plot the graph, we calculate the activity at each time point using the given formula and plot the points on a graph. The x-axis represents the time in minutes, and the y-axis represents the activity in kBq.

Starting with t = 0 minutes, the activity is 4.20 kBq. For each subsequent measurement at intervals of 5 minutes, we calculate the activity using the formula. The resulting data points can be plotted on a graph, connecting them with a decreasing exponential curve.

Note: Since the prompt doesn't specify the unit for time, we assume minutes for consistency with the half-life given in minutes.

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Silver is a conductor. *

Is it true or false

Answers

Answer:

True

Explanation:

Answer:

True.

Explanation:

Silver is a good conductor of electricity because the atoms have many electrons that can be moved.

Without any calculations, determine which solution in each pair is more basic.
Part A
a.0.100 M in KClO
b. 0.100 M in NaF
Part B
a. 0.0100 M in NaBrO
b. 0.0100 M in NaBr
Part C
a. 0.0100 M in HNO_2
b. 0.0100 M in KOH
Part D
a. 0.0100 M in NH_4Cl
b. 0.0100 M in HCN

Answers

In each pair, the solution that contains the weaker conjugate acid is more basic. Without any calculations, we can determine which solution is more basic by identifying the stronger conjugate acid in each pair.

In Part A, KClO is a stronger acid than NaF, so the solution in (b) is more basic in Part B, NaBrO is a stronger acid than NaBr, so the solution in (b) is more basic in Part C, HNO2 is a weaker acid than KOH, so the solution in (b) is more basic in Part D, NH4Cl is a weaker acid than HCN, so the solution in (a) is more basic.

It is important to note that while we did not perform any calculations, this method only works for comparing solutions with the same concentration. If the concentrations were different, we would need to perform calculations to determine which solution is more basic. A

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Based on the information in the table, which of the following arranges the bonds in order of decreasing polarity?

Based on the information in the table, which of the following arranges the bonds in order of decreasing
Based on the information in the table, which of the following arranges the bonds in order of decreasing

Answers

Polarity is the chemical property based on the electric charge and orientation of the poles. Al−O>H−Br>As−S is arranged in decreasing order of polarity. Thus, option d is correct.

What is polarity?

Polarity is a chemical property of the distribution of the electrical charges over their respective atom in the molecule joined by the bonds. The relation between the polarity and the difference in electronegativity is directly proportional.

The electronegativity difference between the elements are:

Al−O = 1.8H−Br = 0.8As−S = 0.4

As the electronegativity difference between Al−O = 1.8 is the highest it will have the highest polarity followed by H−Br = 0.8, and As−S = 0.4, with the lowest polarity.

Therefore, option D. Al−O>H−Br>As−S is arranged in decreasing order of polarity.

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As the age of an object gets older, should the half-life of the probe needed to accurately
estimate its age get relatively shorter or longer?

Answers

Answer:

As the age of an object gets older, the half-life of the probe needed to accurately estimate its age should get relatively longer. This is because the longer the half-life of the probe, the more time it has to decay, and therefore the more accurately it can measure the age of the object. For example, if an object is very old and has very little of the original isotope remaining, a probe with a shorter half-life might not have enough time to decay and give a accurate measurement of the object's age. On the other hand, a probe with a longer half-life would have more time to decay and give a more accurate measurement.

left- and right-handed mirror image molecules are known as

Answers

Left- and right-handed mirror image molecules are known as stereoisomers. Stereoisomers have the same molecular formula and the same connectivity of atoms, but the arrangement of the atoms in space is different. Stereoisomers are formed due to the presence of a chiral center in the molecule

A molecule is said to be chiral if it has a non-superimposable mirror image. Chiral molecules cannot be superimposed on their mirror image. This means that the left- and right-handed mirror images of a chiral molecule are not identical and are not superimposable on each other. Chiral molecules are very important in the field of biology and pharmacology because they interact differently with other chiral molecules in biological systems and can have different biological activities or therapeutic effects.Most biological molecules, such as amino acids, sugars, and DNA, are chiral. Amino acids and sugars are chiral because of the presence of an asymmetric carbon atom in their structures. DNA is chiral because of the helical structure of its double-stranded form. The handedness of chiral molecules can have significant implications for their biological activity, as the interaction between two chiral molecules can depend on their relative handedness.The study of stereoisomers is important in the field of organic chemistry and biochemistry. Understanding the stereochemistry of molecules is essential for understanding their properties and behavior. Stereoisomers can have different physical properties, such as melting point and solubility, and different biological activities, such as receptor binding and enzyme catalysis.

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if 600.0 ml of air is heated from 293 k to 333 k what volume will it occupy

Answers

Answer:

Explanation:

V1= 600.0 mL

T1= 293 K

V2 unknown

T2= 333K

Charles law V1*T2=V2*T1

where V1 and T1 are the initial volume and temperature. V2 and T2 are the final temperature and volume.

V2=(V1*T2)/T1 = ( 600.0*333)/293= 682 mL (with significant figures)(681.911 mL before signifcant figures.)

Mikayla says that air is an element since it has oxygen in it. Jose says that air is a mixture because each part of air keeps its properties. Grant says that both Mikayla and Jose are wrong, because air is a compound. Who is correct and why? Group of answer choices

Answers

Answer: Jose is correct because air is a mixture of gases ( both elements and compounds).

Explanation:

An element consist of only one type of atom and a compound made up of 2 or more types of elements joined together ( by ionic or covalent bonds).

Whereas air around us is a mixture of gases (both elements and compounds) like nitrogen, oxygen, argon, and carbon dioxide, and very small amounts of other gases and water vapors

Hence, Jose is correct because air is a mixture of gases ( both elements and compounds).

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