Answer: \(3Ag^+(aq)+3Cl^-(aq)\rightarrow 3AgCl(s)\)
Explanation:
Complete ionic equation : In complete ionic equation, all the substance that are strong electrolytes and are represented in the form of ions.
The complete ionic equation will be:
\(3Ag^+(aq)+3NO_3^-(aq)+Fe^{3+}(aq)+3Cl^-(aq)\rightarrow 3AgCl(s)+Fe^{3+}(aq)+3NO_3^-(aq)\)
Net ionic equation : In the net ionic equations, we do not not include the spectator ions in the equations.
Spectator ions : The ions present on reactant and product side which do not participate in a reactions. The same ions present on both the sides.
In this equation, \(Fe^{3+}\) and \(NO_3^-\) are the spectator ions.
By removing the spectator ions from the balanced ionic equation, we get the net ionic equation.
The net ionic equation will be:
\(3Ag^+(aq)+3Cl^-(aq)\rightarrow 3AgCl(s)\)
Which of these accurately describes the photoelectric effect?
A. Shining a LOW frequency light over a metal will cause PROTONS to be ejected.
B. Shining a HIGH frequency light over a metal will cause ELECTRONS to be ejected.
C. Shining a LOW frequency light over a metal will cause ELECTRONS to be ejected.
D. Shining a HIGH frequency light over a metal will cause PROTONS to be ejected.
The statement that accurately describes the photoelectric effect is Shining a HIGH frequency light over a metal will cause ELECTRONS to be ejected. That is option B.
What is photoelectric effect?Photoelectric effect is defined as the process by which electrically charged particles are released from or within a material when it absorbs electromagnetic radiation.
The photoelectric effect can also be defined as the ejection of electrons from a metal plate when light falls on it.
Therefore, statement that accurately describes the photoelectric effect is Shining a HIGH frequency light over a metal will cause ELECTRONS to be ejected.
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Which statement best describes what happens when thermal energy of the
air around a fire is transferred to the surrounding air?
O A. The thermal energy is spread out by the surrounding air.
OB. The thermal energy is destroyed over time.
OC. The thermal energy changes to chemical energy.
O D. The thermal energy is destroyed as it changes to chemical energy.
When the thermal energy of the air around a fire is transferred to the surrounding air A. The thermal energy is spread out by the surrounding air.
Thermal energy transfers occur in 3 approaches conduction, convection, and radiation. whilst thermal power is transferred among neighboring molecules that are in touch with each other, which is referred to as conduction.
Thermal strength refers to the power contained inside a system that is liable for its temperature. heat is the go with the flow of thermal electricity. an entire department of physics, thermodynamics, offers how heat is transferred among exceptional systems and how work is accomplished in the manner.
Thermal strength also referred to as heat strength is produced when a rise in temperature reasons atoms and molecules to transport quicker and collide with each other. The energy that comes from the temperature of the heated substance is referred to as thermal strength.
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What are significant figures?
Answer:
Significant figures are the number of digits in a value, often a measurement, that contributes to the degree of accuracy of the value.
Explanation:
All non-zero numbers ARE significant.
Zeros between two non-zero digits ARE significant.
Leading zeros are NOT significant.
Trailing zeros to the right of the decimal are significant.
Trailing zeros in a whole number with the decimal shown significant.
Which of the following is an incorrect representation for a neutral atom?
36Li
613C
3063Cu
1530P
This representation suggests that the element is phosphorus (P) with a mass number of 30, which is incorrect. The correct mass number for phosphorus is approximately 30.97. The incorrect representation for a neutral atom is 36Li
To determine the correct representation for a neutral atom, we need to consider the atomic number (Z) and mass number (A) of the element. The atomic number represents the number of protons in the nucleus, while the mass number represents the sum of protons and neutrons.
Let's analyze the given representations:
36Li:
This representation suggests that the element is lithium (Li) with a mass number of 36, which is incorrect. The correct mass number for lithium is approximately 6.94.
613C:
This representation suggests that the element is carbon (C) with a mass number of 13, which is correct. Carbon has different isotopes, and 13C represents one of its stable isotopes.
3063Cu:
This representation suggests that the element is copper (Cu) with a mass number of 63, which is correct. Copper has different isotopes, and 63Cu represents one of its stable isotopes.
1530P:
This representation suggests that the element is phosphorus (P) with a mass number of 30, which is incorrect. The correct mass number for phosphorus is approximately 30.97.
Therefore, the incorrect representation for a neutral atom is 36Li, as it does not match the known properties of lithium.
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It is difficult to break the ionic bonds in a compound because of the
61. Given the following information:
Ag2 CrO4(s)=2Agt (aq) + CrO4²- (aq)
Ag+ (aq) + e- Ag(s)
find the standard reduction potential at 25°C for the half-reaction
Ksp = 1 × 10-12
E = +0.799 V
Ag2 CrO4(s) + 2e¯ 2Ag(s) + CrO4²- (aq)
Q = Ksp = 1 × 10^(-12).
Substituting the values into the Nernst equation, we have:
0.799 V = E° - (RT/2F) * ln(1 × 10^(-12))
Now, solving for E°:
E° = 0.799 V + (RT/2F) * ln(1 × 10^(-12))
The value of R is the ideal gas constant, T is the temperature in Kelvin, and F is the Faraday constant.
To find the standard reduction potential at 25°C for the half-reaction Ag2CrO4(s) + 2e¯ → 2Ag(s) + CrO4²-(aq), we can use the Nernst equation, which relates the standard reduction potential (E°) to the equilibrium constant (K) and the reaction quotient (Q).
The Nernst equation is given as follows:
E = E° - (RT/nF) * ln(Q)
Given information:
Ksp = 1 × 10^(-12)
E = +0.799 V (standard reduction potential of Ag+ to Ag)
Since the reaction involves the dissolution of Ag2CrO4(s), the reaction quotient Q can be expressed as [Ag+]²/[CrO4²-].
Since the stoichiometry of the reaction is 2:1 for Ag2CrO4 to Ag+, we can say that [Ag+]² = Ksp.
Therefore, Q = Ksp = 1 × 10^(-12).
Substituting the values into the Nernst equation, we have:
0.799 V = E° - (RT/2F) * ln(1 × 10^(-12))
Now, solving for E°:
E° = 0.799 V + (RT/2F) * ln(1 × 10^(-12))
The value of R is the ideal gas constant, T is the temperature in Kelvin, and F is the Faraday constant.
Please note that without specific values for temperature (T) and the ideal gas constant (R), the exact standard reduction potential at 25°C cannot be determined.
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A burning match releases 838.2 J of energy. Convert the energy released by 20 matches to the following energy units: (provide an answer in 4 significant figures)
________ Kilojoules
________ Calories
________ Food Calories
________ calories
________ kcal
Answer:
See explanation
Explanation:
In this case, we can start with the calculation of the total energy released by the 20 matches. One match release 838.2 J of energy ( 1 match = 838.2 J). So:
\(20~matches\frac{838.2~J}{1~match}=16764~J\)
With this in mind, we have to find al the conversion ratios to "Jolues", so:
\(1~KJ=1000~J\)
\(1~Cal=4.184~J\)
\(1~KCal=4184~J\)
\(0.000239~food~calories=1~J\)
Now, we can do the conversions:
\(16764~J\frac{1~KJ}{1000~J}=16.76~KJ\)
\(16764~J\frac{1~Cal}{4.184~J}=4.005x10^3~Cal\)
\(16764~J\frac{1~KCal}{4184~J}=4.007~KCal\)
\(16764~J\frac{0.000239~food calories}{1~J}=4.006~food calories\)
I hope it helps!
Compare the behavior of the mixture of gases with each solitary gas in the presence of flame.
The heat made by a mixture of gases is less than that produced by solitary gases of hydrogen or oxygen.
How are the gases behave in the mixture?The property becomes a solution of a homogeneous mixture. Some of the effects of gas mixtures are easy to control. if we know the composition of the gases in the mix. In gas mixtures, all components in the gas phase can be used separately. The atmosphere is a mixture of different gases. The part, usually present in solution, first has to be atomized in a flame. Premixed combustion flame, a mixture of fuel and oxidant gas, and diffusion. compared to liquid streams, is relatively simple because the bulk characterization of a single phase is implicit. However, when gas. The heat produced by a mixture of gases is less than that produced by solitary gases. of hydrogen or oxygen.
so we can conclude that the flame appears yellow if there are impurities in the air whereas a pure hydrogen gas flame will not produce any smoke.
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Select the conversion factors needed to convert the cost of gas from dollars per gallon to the cost in euros per liter.
3.17 dollars
х
0.946 euros
1L
1 gal
Answer Bank
1.13 euros
1 dollar
1 dollar
1.13 euros
3.7854 L
1 gal
1 gal
3.7854 L
The correct conversion factor would be 0.24 euro per liter
Unit conversion1 dollar = 0.89 euro
Also,
1 gallon = 3.785 liters
Thus, 1 dollar/gallon = 0.89 euro/3.785 liters
If 0.89 euro is for 3.785 liters, 1 liter would be:
1 x 0.89/3.785/= 0.24 euro
Thus, the cost of gas from 1 dollar per gallon would be 0.24 euro per liter
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Pls help i have 0 clue what this even means
Show all work including units and the equation you used to solve. Carbon dioxide gas has a molar mass of 44 g/mol. At 300K and 1.5atm, a sample of carbon dioxide has a volume of 4.5 L. Find the number of moles of the carbon dioxide.
EXTRA POINTS: Find the mass of the carbon dioxide.
Answer: 0.27 moles of CO2 and 11.88 grams of CO2
Explanation: Use the Ideal Gas Law, PV = nRT, substitute the values given and solve.
I can't seem to upload procedure but:
P = 1.5atm
V = 4.5L
n = moles
R = 0.0821gr/mol (when using atm, kPa is 8.31)
T = 300K
Isolate what you don't have, in this case n. Change PV = nRT to PV/RT = n. Substitute the values to get moles. Once you have this, multiply the value by the molar mass of CO2 (44gr/mol) to get the mass of CO2 in grams.
Which statement about members of a homologous series is true
The statement "Each member of a homologous series differs from its nearest neighbors by 14 amu" is true of members about a homologous series.
What are homologous series?In organic chemistry, a homologous series unveils itself as a sequential assembly of compounds exhibiting an identical functional group, boasting akin chemical traits. Within this series, the constituents can either sport a branched or unbranched structure, or deviate through the molecular formula of CH2 and a molecular mass variation of 14u.
This divergence may manifest as the elongation of a carbon chain, as observed in the linear alkanes (paraffins), or as the augmentation in the count of monomers forming a homopolymer, such as amylose.
The entities belonging to a homologous series typically embrace a fixed assortment of functional groups, thereby conferring upon them resemblant chemical and physical characteristics.
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PLEASE HELP!! 74 POINTS
An igneous rock has small, dark crystals. Which statement also accurately describes this rock?
It is an intrusive rock.
It has a coarse texture.
It was found on Earth’s surface.
It was formed from slow cooling.
---------------------------------------------------------
Which is one factor that contributes to the formation of polar, temperate, and tropical zones?
the angle of the Sun’s rays
the direction of seasonal winds
the presence of prevailing winds
the movement of wind near a mountain
Answer:
It was formed from slow cooling.
the angle of the Sun’s rays
Explanation:
Answer:
D. It was formed from slow cooling.
Select True or False: The entropy of a perfectly ordered crystalline substance at 0 K is 0 J/mol. Bloom's Level: Understand
True, the entropy of a perfectly ordered crystalline substance at 0 K is 0 J/mol.
The third law of thermodynamics states that, the entropy of a system approaches a constant value as the temperature of the system approaches absolute zero.
The entropy of any perfectly ordered, crystalline substance at absolute zero temperature is zero. That is, the entropy of a pure, perfect crystalline substance at 0 K is 0 J/K.
Thus, we can conclude that the given statement is true. The entropy of a perfectly ordered crystalline substance at 0 K is 0 J/mol.
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As part of an investigation of the population of foxes on Sunday Gill island a scientist graphed the number of foxes presented on the island over a Spam of 15 years as shown below the study began with the earlier 0 and run until the start of year 15 According to the graph during the witch year the event reduced the carrying capacity of the area
The carrying capacity of the area was reduced in the year 10 according to the graph that shows the number of foxes on the island over a span of 15 years.
The graph shows a population of foxes over a span of 15 years. The y-axis represents the number of foxes on the island, while the x-axis represents time. The study began with the earlier 0 and ran until the start of year 15. According to the graph, the carrying capacity of the area was reduced in the year 10.
In the graph, it is shown that the population of foxes on Sunday Gill island had a significant increase from year 0 to year 3. After year 3, the fox population started to decrease and then remained fairly constant until year 10. After year 10, the population of foxes on the island started to decline more rapidly until the end of the study in year 15
This decline in the population of foxes on the island is most likely due to the reduction in carrying capacity of the area. Carrying capacity refers to the maximum number of individuals that an environment can sustain. When the carrying capacity of an environment is reached, it means that the environment can no longer provide the necessary resources to sustain the population.
There are various factors that can cause a reduction in carrying capacity, such as environmental degradation, competition for resources, or a natural disaster. In this case, it is not clear what caused the reduction in carrying capacity in year 10, but it is likely that it was due to some environmental factor that impacted the availability of resources for the fox population.
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Calculate the standard entropy change
C2H2 (g) + 2H2 (g) → C2H6 (g
C2H2= 201
H2=131
C2H6 = 230
Entropy is a notion that essentially refers to the universe's propensity for chaos or the spontaneous changes that take place in everyday happenings. Here the standard entropy change for the given reaction is -233.
Entropy is typically referred to as a measurement of a system's randomness or disorder. In the year 1850, a German physicist by the name of Rudolf Clausius first proposed this idea. Entropy is a thermodynamic property that is used to characterize how a system behaves in terms of temperature, pressure, entropy, and heat capacity.
Here the standard entropy change is:
Entropy of products - entropy of reactants
ΔS = 230 - (201 + 2 ( 131)) = -233
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Balance the following reaction:
_______ CO₂ + _______ H₂O + heat ↔ _______ C₆H₁₂O₆ + _______ O₂
Please explain!
*Note: If any of the coefficients are the number one. Please, write "1" in the space. Thanks!
Answer:
6CO2+6H2O+heat" C6H12O6+6O2
the best way to balance a chemical reaction is to start with balancing the hydrogen followed by the other elements then lastly oxygen.so in this case if you put a 6 in front of carbon dioxide,water and oxygen you will definitely balance it.cause at the first side you have 6 carbons similar to the product,12 oxygen similar to the product and 18 oxygen similar to the products.
I hope this helps
Answer:
Explanation:
I saw this after answering your other question on the same reaction.
To balance the chemical reaction, look at the reactants and products. As O is part of both products, focus on C and H instead.
On the products side, 1 C6H12O6 has 6 C and 12 H. So that requires the same numbers of C and H on the reactant side because of mass conservation.
That gives 6 CO2 and 6 H2O as the reactants. Counting the number of O in the reactants, there are 6*2 + 6 = 18 O. Subtracting the 6 O in C6H12O6, that leaves 12 O so there are 12/2 = 6 O2 in the products.
Combining the numbers above, the balanced equation is:
___6___ CO₂ + ___6___ H₂O + heat ↔ ___1___ C₆H₁₂O₆ + ___6___ O₂
6. Calculate the mass of each product when 100.0 g of CuCl react according to the reaction
CuCl(aq) → CuCl2(aq) + Cu(s)
What do you notice about the sum of the masses of the products? What concept is being
illustrated here?
Answer:
67.91 g of CuCl2; 32.09 g of Cu.
Explanation:
The two masses add to 100.0 g, the initial amount of starting material, demonstrating the law of conservation of matter.
Which equation shows an increase in entropy?
Hint: Look at the states of matter, g s l, of the chemicals in each equation. A C2H4(g) + H2(g) + C2H6(g) в Caco3(9) + Cao(s) - CO2(g) c Fe(s) + S (s) -+ FeS (s)
The equation C2H4(g) + H2(g) + C2H6(g) → Caco3(s) + Cao(s) + CO2(g) shows an increase in entropy due to the formation of a gas as a product. Option A
In this equation, the reactants on the left-hand side consist of gases (C2H4 and H2), while the products on the right-hand side include a solid (Caco3) and a gas (CO2).
When a reaction involves a change from gaseous to solid or liquid states, there is typically a decrease in entropy because the particles become more ordered and constrained in the solid or liquid phase.
Conversely, when a reaction involves the formation of gases, there is generally an increase in entropy because gases have higher degrees of molecular motion and greater freedom of movement compared to solids or liquids.
In the given equation, the reactants include three gaseous compounds (C2H4, H2, and C2H6), and one of the products is a gas (CO2). Therefore, the overall entropy of the system increases during this reaction.
The equation Fe(s) + S(s) → FeS(s) does not show an increase in entropy. Both the reactants (Fe and S) and the product (FeS) are solids. Since solids have lower entropy compared to gases or liquids, the entropy of the system does not increase in this reaction. Option A
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what is the difference between test tube and boiling tube
Test tubes heat small amounts of liquids while boiling tube boils liquids
Which one of the following salts has the highest molar solubility in water?
Answer:
Correct option is
C
Ag
2
CO
3
; K
sp
=6.2×10
−12
(A) For CaCO
3
,S=
Ksp
=
8.7×10
−9
=9.3×10
−5
M
(B) For CuS,S=
Ksp
=
8.5×10
−45
=9.2×10
−23
M
(C) For Ag
2
CO
3
,S=(Ksp/4)
1/3
=(6.2×10
−12
/4)
1/3
=1.15×10
−4
M
(D) For Pb(IO
3
)
2
,S=(Ksp/4)
1/3
=(2.6×10
−13
/4)
1/3
=4×10
−5
M
Hence, Ag
2
CO
3
has the greatest molar solubility in pure water.
amobarbital sodium react with ethanolic sodium hyrooxide
Amobarbital (like all barbiturates) works by being incontestible to the GABAA receptor at either the alpha or the beta subunit.
What is the mechanism of amobarbital?Amobarbital (like all barbiturates) works by binding to the GABAA receptor at either the alpha or the beta subunit. These are compulsory sites that are distinct from GABA itself and also distinct from the benzodiazepine binding site.
Amobarbital is a barbiturate classified as having a halfway duration of action, meaning that the effects of the drug can last from 4-6 amobarbital increases the effects of benazepril by apparatus: pharmacodynamic synergism.
So we can conclude that Amobarbital, 5-ethyl-5-isoamyl barbituric acid like all barbiturates.
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given the pathways of glycolysis and gluconeogenesis, identify regulatory steps, regulatory molecules, and whether the molecules are activators or inhibitors, especially molecules such as amp, atp, acetyl-coa, citrate, and fructose-2,6-bisphosphate.
Gluconeogenesis and glycolysis are mutually regulated. *AMP: Glycolysis is encouraged because cells need ATP. Citrate and acetyl-CoA reporting on the citric acid cycle. Because the cell is creating energy and intermediates for biosynthetic processes when [C] is high, gluconeogenesis is encouraged.
What do you call molecules?Any atoms joined by chemical bonds are referred to be molecules in general. A molecule consisting of atoms from several elements is referred to as a compound. Molecules make up all chemicals.
Is a person a molecule?The vast array of molecules that make up the human body are all combinations of just a few dozen basic constituents: the periodic table's chemical elements. But each atom's abundance is very different from the others.
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Amount of H2SO4 in 2 litres, having 28% concentration solution
Answer:
The amount of H2SO4 in 2 litres is 560gm.
Explanation:
Given,
mass of sulphuric acid / volume of solution =28%
Therefore, mass of sulphuric acid in 100 ml solution is 28 grams.
We know that,
volume of solution is 2000ml.
Thus,
mass of sulphuric acid in 2000ml is
(28/100) ×2000
=28×20
=560gm
Thus, the mass of sulphuric acid is 560gm.
What is the molar concentration of Zn2+ ions in a solution, if the electrode potential value is 59mV less than the standard electrode potential value at 298 K?
Molar concentration of Zn2+ions in a solution is 3.481 mol/lit
The electrode potential value is 59mV
Temperature=298k
What is electrode potential?
It is a force of galvanic cell. basically it is the difference between an electrolyte and electrode.equation formed- Zn → Zn2+ + 2e
from Nernst equation-
E=E cell - 0.059 log [Zn2+]
[zn2+]=3.481 mol/lit
hence, Molar concentration of Zn2+ions in a solution is 3.481 mol/lit
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When population growth levels off in an ecosystem, it has reached its _________.
it represents the maximum population size a particular environment can support
Two asteroids are 75,000 m apart one has a mass of 8 x 10^7 N what is the mass of the other asteroid
The mass of the asteroid is C. 1.2 x \(10^{12}\) Kg
To find the mass of the other asteroid, we can rearrange the equation for the gravitational force between two objects:
F = (G * m1 * m2) / \(r^{2}\)
where F is the force of gravity, G is the gravitational constant, m1 and m2 are the masses of the two asteroids, and r is the distance between them.
Given that the distance between the asteroids is 75000 m, the force of gravity between them is 1.14 N, and one asteroid has a mass of 8 x \(10^{7}\) kg, we can substitute these values into the equation and solve for the mass of the other asteroid (m2):
1.14 N = (6.67430 × \(10^{-11}\) N \(m^{2}\)/\(Kg^{2}\) * 8 x \(10^{7}\) kg * \(m2\)) / \((75000 m)^{2}\)
Simplifying and solving the equation, we find that the mass of the other asteroid (m2) is approximately 1.2 x \(10^{12}\) kg. Therefore, Option C is correct.
The question was incomplete. find the full content below:
Two asteroids are 75000 m apart one has a mass of 8 x \(10^{7}\) kg if the force of gravity between them is 1.14 what is the mass of the asteroid
A. 3.4 x \(10^{11}\) kg
B. 8.3 x \(10^{12}\) kg
C. 1.2 x \(10^{12}\) kg
D. 1.2 x \(10^{10}\) kg
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What mass of NaCl is needed to produce a 26.4 mol/L with a 1.7 L volume?
we would need 2625.13 grams (or 2.62513 kilograms) of NaCl.
To calculate the mass of NaCl required to produce a 26.4 mol/L solution with a 1.7 L volume, we need to use the formula that relates the mass of solute, moles of solute, and molarity:Molarity (M) = moles of solute / liters of solution Rearranging this formula, we get:moles of solute = Molarity (M) x liters of solutionWe can use this formula to find the moles of NaCl needed:moles of NaCl = 26.4 mol/L x 1.7 L = 44.88 molNow, we can use the molar mass of NaCl to convert from moles to grams. The molar mass of NaCl is 58.44 g/mol:mass of NaCl = moles of NaCl x molar mass of NaClmass of NaCl = 44.88 mol x 58.44 g/mol = 2625.13 gTo produce a 26.4 mol/L solution with a 1.7 L volume.
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which acide will have more strength
out of two acids of pH
value 2
and 5 why
Ph 2 will ahve more strength due to the fact that its more acidic compared to pH 5.
the lower the number of a pH, the more it is heading towards being acidic, but the higher the number, the more it heads towards being an alkali. here is a ppt i made along time ago. hope it can help you . have a nice day
_Al(OH)3 + __H2SO4 →
_Al2(SO4)3 +___ H2O
In this equation, two molecules of aluminum hydroxide react with three molecules of sulfuric acid to produce one molecule of aluminum sulfate and six molecules of water.
What is Molecules?
A molecule is a group of two or more atoms that are chemically bonded together. Atoms can combine to form molecules by sharing electrons between them, forming a covalent bond. Molecules can also be formed by the attraction between oppositely charged ions, known as ionic bonding.
Molecules can be made up of atoms of the same element or atoms of different elements. For example, oxygen gas (O2) is a molecule made up of two oxygen atoms, while water (H2O) is a molecule made up of two hydrogen atoms and one oxygen atom.
The balanced chemical equation for the reaction between aluminum hydroxide and sulfuric acid is:
2Al(OH)3 + 3H2SO4 → Al2(SO4)3 + 6H2O
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3. A Wilkinson’s catalyst is widely used in the hydrogenation of alkenes. Show a catalytic cycle, including: i. chemical structure of the catalyst, with complete stereochemistry ii. molecular geometry of catalyst iii. type of reactions involved iv. the appropriate starting material, reagent and solvent v. major and minor end-products vi. all intermediates, for each reaction stated in (iii)
We can see here that the catalytic cycle for the hydrogenation of alkenes using Wilkinson's catalyst involves several steps.
What are the steps involved?Here's an overview of the catalytic cycle, including the necessary details:
i. Chemical structure of the catalyst:
Wilkinson's catalyst, also known as chloridotris(triphenylphosphine)rhodium(I), has the following chemical structure: [RhCl(PPh3)3]
ii. Molecular geometry of the catalyst:
The Wilkinson's catalyst has a trigonal bipyramidal geometry around the rhodium center. The three triphenylphosphine (PPh3) ligands occupy equatorial positions, while the chloride (Cl) ligand occupies an axial position.
iii. Type of reactions involved:
The catalytic cycle involves several reactions, including:
Oxidative addition: The rhodium center undergoes oxidative addition, reacting with molecular hydrogen (H2) to form a dihydride intermediate.Alkene coordination: The alkene substrate coordinates to the rhodium center, forming a π-complex.Hydrogenation: The coordinated alkene undergoes hydrogenation, resulting in the addition of hydrogen atoms to the double bond and formation of a metal-alkyl intermediate.Reoxidation: The metal-alkyl intermediate reacts with a hydrogen molecule to regenerate the rhodium dihydride species.iv. Starting material, reagent, and solvent:
The starting material is an alkene, and the reagent is Wilkinson's catalyst ([RhCl(PPh3)3]). The reaction is typically carried out in a suitable solvent, such as dichloromethane (CH2Cl2) or tetrahydrofuran (THF).
v. Major and minor end-products:
The major end-product of the hydrogenation reaction is the fully saturated alkane, resulting from the addition of hydrogen across the double bond. The minor end-product may include cis- or trans-configured alkanes if the original alkene substrate possesses geometric isomers.
vi. Intermediates:
The intermediates in the catalytic cycle include:
Rhodium dihydride complex: [RhH2(PPh3)3]Alkene-Rhodium π-complex: [Rh(η2-alkene)(PPh3)3]Metal-alkyl intermediate: [Rh(alkyl)(PPh3)3]These intermediates play a crucial role in facilitating the hydrogenation reaction and enabling the catalytic cycle to proceed.
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